This poster for the Rocky Horror Picture Show, and has a mask created from type face over layed across a character from the film (which looks to have been traced and filled with simple colours). This on the chosen background creates an eye catching graphic.
The first of two appearances by the 1934 Boris Karloff/Bela Lugosi horror The Black Cat, taken from the Poe story. This is the "Style D" one-sheet, which went for $286,800 in 2007. Look at those cat's eyes!