Prince Johann Georg of Saxony's first wife, Princess Maria Isabella of Wurttemberg, they wed on 5 April 1894. Seen here wearing a different diamond and pearl tiara to her sucessor. She died on 24 May 1904
Princess Caroline Mathilde of Saxe-Coburg-Gotha. I THINK this Caroline Mathilde is the eldest child of Hereditary Prince Johann Leopold. I'm not totally sure because there were a few Caroline Mathilde's in Coburg and the other German Houses.