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Paint shoes??? remove finish with 100% acetone, rub lighty with steel wool (#000), wipe with microfiber rag, cover heel with painters tape if don't want to change that color, stuff shoe with newspaper, spray...she used Krylon Dual but said she'd probably use Rust-oleum Fabric and Vinyl spray, 4-5 light coats, dry in between, several coats Mod-Podge...

Jimmy Choo Ombre Shoes DIY ---- interesting idea...I would also tape-off heel and sole edges to retain original color.